You got it worng I think?
You put picture in the app from iTunes, then transfer the picture off the app to your iPod!
Reason for this idea is that you dont need to sync your photos from iTunes to place to your iPhone cause often it well erase photos that arent sync to other ppl computer.
1. Picture in pc > go to iTunes > app on iPod (scroll down)
2. Open iPod app > get picture > send to iPod photos
The End
Jezzy M.D. about
DC Copy